What are the Differences Between Lithium Batteries and Regular Batteries

by Emma Larson on Nov 08 2024

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    Emma Larson
    Emma Larson has over 15 years of industry experience in energy storage solutions. She is passionate about sharing her knowledge of sustainable energy and focuses on optimizing battery performance for golf carts, RVs, solar systems and marine trolling motors.

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    Batteries are electrochemical devices that convert chemical energy into electrical energy and are important for a wide range of devices, from remote controls for household appliances to industrial systems such as electric vehicles. Batteries are categorized as primary (non-rechargeable) or secondary (rechargeable) based on their chemical composition and design.

    Understanding the differences between lithium batteries and more common batteries, such as alkaline, lead-acid, and lithium batteries, can help you make informed purchasing decisions based on your specific needs.

    What are the Differences Between Lithium Batteries and Regular Batteries

    What Are Regular Batteries?

    Regular batteries, often referred to as conventional batteries, encompass a variety of battery types suited to specific applications, including alkaline, lead-acid, carbon-zinc, nickel-cadmium (Ni-Cd), and nickel-metal hydride (Ni-MH) batteries.

    Tips: Although ordinary traditional lead-acid batteries are still used by most people due to their mature battery technology and affordable prices, due to some characteristics of ordinary batteries such as high maintenance costs and short lifespan, and with the continuous advancement of lithium-ion battery technology and the popularization of its use, the use of ordinary batteries in some specific applications, such as RVs, golf carts or home solar energy systems, has gradually been replaced by lithium batteries.

    Alkaline Batteries

    These primary batteries use zinc and manganese dioxide electrodes with an alkaline electrolyte (potassium hydroxide). Typically costing $0.5-$2 per unit, they power household devices like remote controls, flashlights, and toys due to their affordability and availability. Each alkaline cell typically provides about 1.5V of output voltage. However, their performance degrades in extreme temperatures, such as below 32°F.

    Lead-Acid Batteries

    These secondary batteries feature lead dioxide and sponge lead electrodes in a sulfuric acid electrolyte. They deliver high cold cranking amps (CCA), making them ideal for automotive starters, small-scale uninterruptible power supplies (UPS), and backup power systems.

    Carbon-Zinc Batteries

    These primary batteries, also known as zinc-carbon batteries, use zinc as the anode and manganese dioxide as the cathode with a zinc chloride electrolyte. They are less expensive than alkaline batteries (typically $0.3-$1 per unit) and are used in low-power drain devices like clocks, smoke alarms, and basic toys, though they offer lower capacity and shorter shelf life compared to alkaline batteries.

    Nickel-Cadmium (Ni-Cd) Batteries

    These rechargeable batteries use nickel oxide hydroxide and cadmium electrodes with a potassium hydroxide electrolyte. Known for their durability and ability to handle high discharge rates, Ni-Cd batteries are used in power tools, cordless phones, and emergency lighting. However, their use has declined due to cadmium's environmental toxicity and the memory effect, which reduces capacity if not fully discharged before recharging.

    Nickel-Metal Hydride (Ni-MH) Batteries

    These rechargeable batteries use a nickel oxide hydroxide cathode and a hydrogen-absorbing alloy anode. Offering higher capacity than Ni-Cd, such as 2,000-3,000mAh for AA size, they are used in household devices like digital cameras and hybrid vehicles. Ni-MH batteries are more environmentally friendly than Ni-Cd but have a higher discharge rate (3-5% per month) and shorter cycle lifes (500-1,000 cycles).

    What Are Lithium Batteries?

    Lithium batteries encompass various types, including lithium-ion and lithium-polymer batteries. Their high performance, lightweight design, and extended lifespan make them an integral part of modern battery technology across a wide range of applications. Typical lithium-ion cells have a nominal voltage of about 3.2–3.7V per cell, depending on chemistry (like LiFePO4 ≈ 3.2V, NCM/NCA ≈ 3.6–3.7V). Lithium batteries can also be subdivided based on their shape and chemical composition

    Lithium-Ion Batteries

    These rechargeable batteries use lithium compounds such as lithium cobalt oxide, lithium iron phosphate, or nickel cobalt manganese (NCM)/nickel cobalt aluminum (NCA) as the positive electrode and carbon as the negative electrode. They have high energy density and can power electronic devices such as smartphones and laptops, electric vehicles, and renewable energy storage systems.

    Lithium-Polymer Batteries

    Similar to lithium-ion, these use a polymer electrolyte for a flexible form factor, ideal for compact, lightweight applications like drones and wearable technology.

    According to shape, it can be divided into:

    1. Cylindrical batteries: Examples include the 18650 (18 mm diameter, 65 mm length), 2,000-3,500 mAh, and 21700 (4,000-5,000 mAh). These batteries utilize a robust tubular design. Due to their high energy density and standardized manufacturing, their cylindrical shape allows for efficient heat dissipation and is widely used in electric vehicles, power tools, and laptops.
    2. Prismatic batteries: Prismatic batteries are rectangular in shape. With capacities ranging from 20 Ah to over 200 Ah, they are suitable for applications requiring scalable power solutions, such as energy storage units and large-scale systems like electric vehicle battery packs, maximizing space efficiency.
    3. Pouch batteries: These batteries utilize a flexible, lightweight pouch rather than a rigid casing. Typically made of lithium polymer, they offer high energy density and can be customized to fit smartphones, wearables, and household devices like drones. However, they require careful handling to prevent damage.

    According to Chemistry, it can be divided into:

    1. Lithium cobalt oxide (LCO): LCO batteries are known for their high energy density of approximately 200 Wh/kg. However, their cycle life is typically limited to 500-1,000 cycles, and their thermal stability is low, requiring robust safety systems. They are commonly used in electronic devices such as smartphones and cameras.
    2. Lithium iron phosphate (LFP): LFP batteries have an energy density of approximately 150 Wh/kg, offer good safety, and a long cycle life of 2,000-4,000 cycles. Their thermal stability makes them less susceptible to thermal runaway, making them commonly used in electric vehicles and renewable energy storage.
    3. Nickel cobalt manganese (NCM) and nickel cobalt aluminum (NCA): These chemistries offer approximately 180 Wh/kg and a cycle life of 1,000-2,000 cycles, making them suitable for electric vehicles and power tools. However, they require careful management to ensure safety.

    What Are The Differences Between Lithium Batteries And Regular Batteries

    Both commonly used batteries have their own advantages and disadvantages. Understanding their key differences can help you better choose the best battery for your needs.

    Chemical Composition

    The electrode materials of lithium batteries usually use composite oxides such as lithium cobalt oxide (LiCoO₂), lithium nickel oxide (LiNiO₂), and lithium manganese oxide (LiMn₂O₄) as the positive electrode, and graphite or silicon-based materials as the negative electrode. This design allows lithium ions to reversibly embed and extract from the crystal structure of the electrode material during charging and discharging, resulting in higher conversion efficiency.
    Ordinary batteries use metals like zinc or lead that undergo physical phase changes or dissolution, reducing efficiency and accelerating electrode degradation.

    Voltage and Power Output

    Lithium batteries provide higher voltage per cell (3.2V for LFP, up to 3.7V for NCM) compared to alkaline (1.5V) or lead-acid (2V per cell). They maintain a stable voltage throughout discharge, unlike alkaline batteries that gradually decline, ensuring consistent performance in demanding applications like medical equipment or electric vehicles.
    This voltage advantage also enables lithium batteries to achieve higher total pack voltages (like 48V, 72V) by connecting fewer cells in series, improving efficiency and compactness.

    High Energy Density and High Power Output

    Energy density is a key metric for battery performance and directly determines the lifespan of a device on a single charge. Lithium-ion batteries offer significant advantages in this regard. Their energy density (energy stored per unit weight) typically reaches 100-265Wh/kg, compared to only 30-50Wh/kg for standard alkaline and lead-acid batteries. This means that for the same weight, lithium-ion batteries can store 3-5 times more energy than standard batteries. Furthermore, lithium-ion batteries boast an energy conversion efficiency exceeding 95%, compared to only 70-85% for standard lead-acid batteries. This high efficiency translates to less energy waste and lower heat generation, which is particularly advantageous during rapid charging and high-current discharge.

    Lifespan and Durability

    Battery life is always a key concern for consumers, and in this respect, lithium-ion batteries differ fundamentally from conventional batteries. Cycle life refers to the number of charge and discharge cycles a battery can complete before its capacity drops to 80% of its rated value. Lithium-ion batteries typically reach 2,000-4,000 cycles, while lead-acid batteries only offer 300-500 cycles. Alkaline batteries are generally non-rechargeable, and even those that are rechargeable can only be used approximately 300 times. This durability makes lithium-ion batteries more cost-effective in the long term. Furthermore, lithium-ion batteries have a lower discharge rate of only 1-3% per month, compared to 5-10% for alkaline batteries and 3-5% for lead-acid batteries, extending battery life. Furthermore, the stable voltage output of lithium-ion batteries throughout the discharge process helps extend the use of high-performance devices.

    Initial Budget and Long-Term Costs

    In terms of initial cost, lithium batteries are significantly higher than standard batteries. For a storage system of the same capacity, lithium batteries are two to three times more expensive than lead-acid batteries, and even more expensive than alkaline batteries. For example, a typical 12V 100Ah energy storage battery pack costs approximately $500-1,000 USD, while a comparable lead-acid battery costs approximately $150-300 USD. This price difference is primarily due to material costs (metals like lithium and cobalt are relatively expensive) and production processes (lithium batteries require cleanrooms and sophisticated control systems). In the long run, lithium batteries require no regular maintenance or watering, and their cycle life of up to 2,000-4,000 cycles reduces replacement and maintenance costs, making them more cost-effective over time.

    Comparison: Lithium Batteries vs Regular Batteries

    You can also compare the information in the following table to help you more intuitively and clearly understand the differences in key parameters between ordinary batteries and lithium batteries:

    Feature Lithium Batteries Regular Batteries (Alkaline / Lead-Acid)
    Rechargeability Rechargeable (secondary cells) Mostly non-rechargeable (alkaline), lead-acid is rechargeable
    Cell Voltage 3.2–3.7V per cell ~1.5V (alkaline), ~2V (lead-acid)
    Energy Density 150–250 Wh/kg 80–120 Wh/kg (alkaline), 30–50 Wh/kg (lead-acid)
    Cycle Life 2,000–4,000 cycles 300–500 cycles (lead-acid), single-use for alkaline
    Self-Discharge Rate 1–3% / month 5–10% (alkaline), 3–5% (lead-acid)
    Weight Lightweight Heavier (especially lead-acid)
    Low-Temperature Performance Performs well in cold climates; LFP retains capacity down to −4°F Poor cold performance; alkaline capacity drops below 32°F
    Ideal Applications High-performance devices (EVs, solar storage, golf carts, RVs) Low-drain household electronics (remotes, flashlights)
    Environmental Impact Recyclable (≥90%) Contains toxic materials (lead, cadmium), disposable waste

    How to Choose Between Lithium and Regular Batteries?

    Choosing the right battery type depends on your specific application needs. By evaluating key factors such as power requirements, cost, size, weight, safety, and environmental impact, we can help you make a purchasing decision based on your needs.

    Power and Performance Needs

    For low-power devices like remote controls, clocks, or smoke alarms, common batteries like alkaline or carbon-zinc batteries are often sufficient because they are affordable and offer sufficient performance for intermittent use. Lithium-ion batteries, on the other hand, excel in high-performance applications like electric vehicles, drones, solar systems, or ships, where their higher energy density and stable voltage output ensure reliable, continuous power delivery.

    Size and Weight Constraints

    Lithium-ion batteries feature a lightweight design, compact size, and low weight, making them ideal for space-constrained equipment such as RVs and electric golf carts. For example, Vatrer Battery also offers mini golf cart batteries and narrow-profile lithium-ion batteries for golf carts. Traditional batteries, particularly lead-acid batteries, are heavier and more suitable for stationary applications where weight is less critical, such as car starters or UPS systems.

    Safety Requirements

    Lithium batteries have a high energy density and pose a risk of thermal runaway (overheating), so they require careful handling. It's recommended to purchase high-quality lithium batteries equipped with a battery management system (BMS) and compliant with standards such as UL or CE for enhanced safety. Standard batteries, such as alkaline batteries, pose a risk of leakage that could damage household devices, while nickel-cadmium batteries pose an environmental toxicity risk due to their cadmium content. Lead-acid batteries require proper handling to prevent acid leaks.

    Cost and Long-Term Value

    Conventional batteries, particularly alkaline and carbon-zinc batteries, have lower initial costs, but their limited cycle life necessitates frequent replacement, making them more suitable for short-term, low-power applications. While lithium batteries have a higher initial cost, their purchase cost is declining as of 2025, and they offer a longer lifespan (2,000-4,000 cycles), minimizing the cost per use over the long term.

    Environmental Impact: More than 90% of the materials in lithium batteries are recyclable. Although the recycling process involves water use and ecosystem issues, it can still effectively reduce waste. Ordinary batteries, especially lead-acid and nickel-cadmium batteries, have toxic chemical compositions and therefore require more careful handling.

    Conclusion

    Lithium-ion batteries deliver higher voltage, greater energy density, and longer lifespan than conventional batteries, making them the preferred option for modern electric mobility and renewable energy applications. Conventional alkaline or lead-acid batteries remain useful for cost-sensitive, low-drain devices.
    Vatrer Battery offers certified, high-quality lithium-ion solutions (CE/FCC) for RVs, boats, trolling motors, golf carts, and home solar systems. Explore Vatrer Battery’s 12V, 36V, and 48V lithium battery series for a safe, efficient, and durable upgrade tailored to your power needs.

    FAQs

    When Should I Choose Lithium Over Alkaline For Devices?

    You should choose lithium batteries when your device requires high energy output, long runtime, or consistent voltage performance. Lithium batteries are ideal for power-hungry devices such as golf cart, RVs, and solar system. They perform reliably in extreme temperatures and have a much longer shelf life, up to ten years, compared with alkaline batteries. In contrast, alkaline batteries are better suited for low-drain household electronics like remote controls or clocks, where power demand is minimal and replacement costs are low.

    How Do Lithium Battery Chemistries Differ From Each Other?

    Not all lithium batteries are the same. Their chemistry determines performance, safety, and ideal applications.

    Lithium cobalt oxide (LCO) offers high energy density for small electronics, while lithium iron phosphate (LFP) provides excellent thermal stability and long cycle life, making it a preferred option for electric vehicles and solar storage.

    Nickel cobalt manganese (NCM) and nickel cobalt aluminum (NCA) chemistries balance power and lifespan for demanding uses like power tools and e-mobility.

    Understanding these differences helps match the right lithium chemistry to your equipment's voltage, weight, and endurance needs.

    Safety And Disposal Best Practices For Lithium Batteries

    Lithium batteries are generally safe when properly designed and handled, but users should still follow safety standards. Always purchase batteries with built-in Battery Management Systems (BMS) that prevent overcharging, overheating, or short-circuiting. Avoid puncturing, crushing, or exposing batteries to fire or water.

    For disposal, never throw lithium batteries into household trash. Instead, bring them to certified battery recycling centers or hazardous-waste collection sites to prevent environmental contamination. Proper handling extends battery life and ensures compliance with environmental regulations.

    How Temperature Affects Lithium Versus Alkaline Performance

    Temperature plays a major role in battery performance. Lithium batteries maintain stable capacity even in cold environments, operating effectively down to -4°F, which makes them ideal for outdoor or winter applications. They also handle heat better, with minimal expansion or leakage. Alkaline batteries, however, lose capacity rapidly in low temperatures and may leak when exposed to prolonged heat or humidity. In general, lithium batteries provide consistent voltage output and longer runtime across a wider temperature range than alkaline alternatives.

    Cost Comparison And Lifespan For AA Lithium Vs Alkaline

    AA lithium batteries cost more upfront, typically two to three times the price of standard alkaline battery, but their longevity and efficiency make them more economical over time. A single lithium AA battery can last up to 5-8 times longer than an alkaline one in high-drain devices. Moreover, lithium batteries have a shelf life of around ten years and maintain power even after long storage, while alkaline batteries may start to degrade after a few years. Therefore, for critical devices or infrequent access installations, lithium batteries offer a better cost-to-performance ratio in the long term.

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